De Novo Synthesis of Carbohydrates

“A Unified Strategy for the Synthesis of Aldohexoses by Boronate Assisted Assembly of CH2X2 derived C1-Building Blocks“ by Sujenth Kirupakaran, Glib Arago and Christoph Hirschhäuser Dedicated to Prof. Dr. . Schmalz Paper available free of charge DOI: Read online: Read PDF: Timecodes: 0:00 Introduction into carbohydrates and their biological relevance 1:10 Synthesis of carbohydrates 2:03 Sharpless: De Novo Synthesis of Aldohexoses 2:32 Payne Rearrangement 3:20 Pummerer Rearrangement 4:18 A C1-based approach 5:07 Matteson Homologation and Synthesis of Ribose 10:11 Our Plan 11:23 Synthesis of Allitol 14:74 Synthesis of Glucitol/Gulitol 17:29 Synthesis of Mannitol 20:32 Finishing the sugar 22:05 Vinylmetal species from CH2X2 24:16 Want to know more?